Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Trade name : Pickling Paste 4 120 T Revision date : 06.10.2015 Version (Revision) : 3.0.0 (2.1.0) Print d ate : 27.11.2015Page : 1/ 8( EN / D ) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1Product identifier Pickling Paste 4 120 T (CP5030) 1.2Relevantidentifiedusesof thesubstanceormixtureand usesadvised againstEtchant and acids 1.3Detailsof thesupplierofthesafety datasheetSupplier (manufacturer/importer/only representative/downstream user/distributor) Deutsche Derustit GmbH Street: Emil-von-Behring-Str. 4 Postal code/city: 63128 Dietzenbach Telephone : +4960744903-0 Telefax : +4960744903-33 E-mail : info@derustit.de 1.4Emergency telephone number+491705876215 SECTION 2: Hazards identification 2.1Classificationof thesubstanceormixtureClassification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 1 ; H310-Acute toxicity (dermal) : Category1;Fatalincontactwithskin.Acute Tox. 3 ; H 331 -Acute t oxicity ( inhalative) : C ategory 3 ; Toxicif inhaled. Acute Tox. 2 ; H300-Acute toxicity (oral) : Category2;Fatalifswallowed.Eye Dam. 1 ; H318 -Serious eye damage/eye i rritation : Category 1 ; Causes serious eye damage. Skin Corr. 1A ; H314 -Skin corrosion/irritation : Category 1A ; Causes severe skin burns and eye damage. 2.2Label elements Labellingaccordingto Regulation(EC)No. 1272/2008[CLP]Hazard pictogramsSkull and crossbones ( GHS06) · C orrosion ( GHS05) Signal word Danger Hazard components for labelling HYDROFLUORIC ACID 16 % ; CAS No. : 7664-39-3 NITRIC ACID 7 % ; CAS No. : 7697-37-2 Hazard statements H300+H310 Fatal i f swallowed or i n contact with skin. H331 Toxic i f i nhaled. H314 Causes severe skin burns and eyedamage.Specialised Welding Products LtdUnit 1, Farringdon Industrial Centre, FarringdonNr Alton, Hants GU34 3DD, United KingdomTel:+44 (0)1420 588180Fax:+44 (0)1420 588184Email:sales@swp.uk.netEmergency Telephone Number: +44(0)1420588180(officehoursonly)Safety Data SheetStandard Pickling Pasteaccording to Regulation (EC) No. 1272/2008 [CLP]Part No: 1669Date: 27/11/2015Page No: 1 of 8
Safety Data SheetStandard Pickling Pasteaccording to Regulation (EC) No. 1272/2008 [CLP]Part No: 1669Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Trade name : Pickling Paste 4120 T Revision date : 06.10.2015 Version (Revision) : 3.0.0 (2.1.0)Print d ate : 27.11.2015Page : 2/ 8( EN / D ) PrecautionarystatementsP260 Do n ot breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P310ImmediatelycallaPOISONCENTER/doctor/.... P321 Specific t reatment ( see chapter 4 on this label). P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P305+P351+P338IF INEYES: Rinse cautiouslywithwater for severalminutes. Removecontactlenses,ifpresentand easyto do. Continue rinsing. P303+P361+P353IF ON SKIN(or hair): Takeoffimmediatelyallcontaminated clothing.Rinseskin with water/shower.P403+P233 Store i n a well-ventilated place. Keep container tightly closed.P405 Store locked up. 2.3Other hazards NoneSECTION 3: Composition / information on ingredients 3.2MixturesHazardous ingredientsHYDROFLUORIC ACID ; EC No. : 231-634-8; CAS No. : 7664-39-3 Weight fraction : ≥ 15 -< 20 % Classification 1272/2008 [CLP] : Acute Tox. 2 ; H300 Acute Tox. 1 ; H310 Acute Tox. 2 ; H330 Skin Corr. 1A ; H314 Eye Dam. 1 ; H318 NITRIC ACID;EC No. :231-714-2;CASNo.:7697-37-2 Weight fraction : ≥ 5 -< 10 % Classification 1272/2008 [CLP] : Ox. Liq. 3 ; H272Met. Corr. 1 ; H290 Skin Corr. 1A ; H314 Eye Dam. 1 ; H318 Additional informationFulltext ofH-andEUH-phrases:seesection 16.SECTION4:Firstaid measures4.1Description of first aid measures General informationImmediate m edical t reatment re quired because corrosive injuries that are not treated are hard to cure. Provide fresh air. If breathing i s irregular o r stopped, administer a rtificial respiration. No di rect artificial respiration to be given by first aider. Remove victim out of the danger area. Firstaider: Payattentiontoself-protection!Ifunconscious placeinrecovery position and seek medical advice. Symptoms maydevelop severalhours following exposure;medicalobservation t herefore n ecessary f or at l east 4 8 hours. In caseof skin contactAfter contact with skin, wash immediately with plenty of water and soap. Calcium gluconate solution Immediate medical t reatment re quired because corrosive i njuries that are not treated are hard to cure. After eye contactIn case of contact w ith e yes flush i mmediately w ith plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an o phthalmologist. After ingestion Rinse mouth immediately and drink plenty of water. If swallowed, immediately drink: Calcium gluconate solution If swallowed danger o f perforation of t he e sophagus and the stomach (strong corrosive effects). Give sodium sulfate as laxative (1tablespoon in 1 glass of water).Callaphysicianimmediately. Date: 27/11/2015Page No: 2 of 8